全文获取类型
收费全文 | 49698篇 |
免费 | 4404篇 |
国内免费 | 2097篇 |
专业分类
电工技术 | 2833篇 |
技术理论 | 7篇 |
综合类 | 3244篇 |
化学工业 | 8259篇 |
金属工艺 | 2920篇 |
机械仪表 | 3204篇 |
建筑科学 | 3531篇 |
矿业工程 | 1582篇 |
能源动力 | 1531篇 |
轻工业 | 3108篇 |
水利工程 | 776篇 |
石油天然气 | 3138篇 |
武器工业 | 464篇 |
无线电 | 5829篇 |
一般工业技术 | 6363篇 |
冶金工业 | 2418篇 |
原子能技术 | 687篇 |
自动化技术 | 6305篇 |
出版年
2024年 | 107篇 |
2023年 | 877篇 |
2022年 | 1276篇 |
2021年 | 2093篇 |
2020年 | 1612篇 |
2019年 | 1334篇 |
2018年 | 1530篇 |
2017年 | 1768篇 |
2016年 | 1579篇 |
2015年 | 2055篇 |
2014年 | 2652篇 |
2013年 | 3183篇 |
2012年 | 3343篇 |
2011年 | 3594篇 |
2010年 | 3023篇 |
2009年 | 2891篇 |
2008年 | 2883篇 |
2007年 | 2736篇 |
2006年 | 2620篇 |
2005年 | 2239篇 |
2004年 | 1578篇 |
2003年 | 1357篇 |
2002年 | 1355篇 |
2001年 | 1160篇 |
2000年 | 1139篇 |
1999年 | 1144篇 |
1998年 | 957篇 |
1997年 | 810篇 |
1996年 | 754篇 |
1995年 | 582篇 |
1994年 | 493篇 |
1993年 | 330篇 |
1992年 | 264篇 |
1991年 | 195篇 |
1990年 | 171篇 |
1989年 | 134篇 |
1988年 | 111篇 |
1987年 | 57篇 |
1986年 | 56篇 |
1985年 | 34篇 |
1984年 | 28篇 |
1983年 | 23篇 |
1982年 | 24篇 |
1981年 | 14篇 |
1980年 | 9篇 |
1979年 | 6篇 |
1977年 | 3篇 |
1976年 | 6篇 |
1970年 | 2篇 |
1959年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
81.
A high strain rate multi-directional impact forging(MDIF) was applied to a solutionized Mg-Gd-Y-Zr alloy in the temperature range of 350-500℃.Results demonstrate that the dominant deformation mode is twinning at a temperature below 400℃,whereas at a medium temperature of 450℃ considerable continuous dynamic recrystallization was promoted by{10-12} extension twins.At a higher temperature of 500℃,twinning activation was suppressed.New DRX grains were observed but their sizes were much bigger than those resulting from the MDIFed 50 passes at 450℃,which are ascribed to the larger grain boundary mobility and atomic diffusion at 500℃.Moreover,a non-basal weak texture was gained afterward MDIF at each temperature,which is credited to the MDIF process and the minor strain applied in each pass. 相似文献
82.
Yangmin Kuang Lunxiang Zhang Yongchen Song Lei Yang Jiafei Zhao 《American Institute of Chemical Engineers》2020,66(4):e16859
Quantitatively characterizing the seepage features is critical important for multi-fluid flow in gas hydrate accumulations; however, limited researches concern water permeability during hydrate phase transition. In this work, nuclear magnetic resonance (NMR) measurement is employed to observe the in situ formation and dissociation of tetrahydrofuran (THF) hydrate in porous media. Results indicate that the relative free water and bound water consumption during hydrate phase transition can affect the seepage features of sediments. In addition, we investigate the growth habits of THF hydrate in quartz glass sand and find the growth pattern of the hydrate transforms from suspension to cementation when its saturation exceeds approximately 35%. The Tokyo model shows that the hydrate are heterogeneous distribution of pore-filling and likely to evolve in larger pores; The findings clearly show that NMR is an efficient and direct technique for investigating the seepage characteristics during hydrate phase transition as well as pore fluid distribution in sediments. 相似文献
83.
Shengqiang Liu Shiyou Zhang Ning Mao Zhen Song Quanlin Liu 《Journal of the American Ceramic Society》2020,103(12):6793-6800
Broadband near-infrared (NIR) phosphors have received increasing attention for fabricating phosphor-converted light-emitting diodes (pc-LEDs) as NIR light source. Most of the reported broadband NIR phosphors originate from Cr3+ in weak crystal field environments. Herein, we report a luminescent material, MgAlSiN3:Mn2+ with CaAlSiN3-type structure, demonstrating that broadband deep-red-to-NIR emission can be achieved via doping Mn2+ into crystallographic sites with strong crystal field in inorganic solids. This phosphor is synthesized via easy-handle solid-state reaction, and the optimized sample, (Mg0.93Mn0.07) AlSiN3 shows an emission band with peak at ~754 nm, FWHM of 150 nm, and internal quantum efficiency of 70.1%. The photoluminescence intensity can further be enhanced by co-doping Eu2+ as sensitizer. This work provides a new strategy for discovering new broadband NIR phosphors using Mn2+ in strong crystal field as luminescence center. 相似文献
84.
Kang Du Jun Fan Zheng-Yu Zou Xiao-Qiang Song Wen-Zhong Lu Wen Lei 《Journal of the American Ceramic Society》2020,103(11):6369-6377
Low-permittivity Ca1−xSrxSnSiO5 (0 ≤ x ≤ 0.45) microwave dielectric ceramics were prepared via traditional state-reaction at 1400°C-1450°C for 5 hours. Moreover the microwave dielectric properties of SnO2 ceramic were obtained for the first time. SnO2 ceramic was difficult to densify, and SnO2 ceramic (ρrel = 65.1%) that was sintered at 1525°C exhibited the optimal microwave dielectric properties of εr = 5.27, Q × f = 89 300 GHz (at 14.5 GHz), and τf = −26.7 ppm/°C. For Ca1−xSrxSnSiO5 (0 ≤ x ≤ 0.15) ceramics, Sr2+ could be dissolved in the Ca2+ site of Ca1−xSrxSnSiO5 to form a single phase, and the partial substitution of Ca2+ by Sr2+ could improve the microwave dielectric properties of CaSnSiO5 ceramic. Secondary phases (SnO2 and SrSiO3) appeared at 0.2 ≤ x ≤ 0.45 and could adjust the abnormally positive τf value of CaSnSiO5 ceramic. The highest Q × f value (60 100 GHz at 10.4 GHz) and optimal microwave dielectric properties (εr = 9.42, Q × f = 47 500 GHz at 12.4 GHz, and τf = −1.2 ppm/°C) of Ca1−xSrxSnSiO5 ceramics were obtained at x = 0.05 and 0.45, respectively. 相似文献
85.
Yifeng Xu Bingkun Hu Jining Liu Kai Tao Ranran Wang Yang Ren Xiaofeng Zhao Jijin Xu Xuefeng Song 《Journal of the American Ceramic Society》2020,103(2):1281-1292
Microcystins (MCs) is a harmful toxin generated by blue-green algae in water, which has seriously threatened the ecological safety of water and human body. It is urgent to develop new catalysts and techniques for the degradation of MCs. A feasible electrostatic self-assembly method was carried out to synthesize BiVO4/g-C3N4 heterojunction photocatalyst with highly efficient photocatalytic ability, where BiVO4 nanoplates with exposed {010} facets anchored to the g-C3N4 ultrathin nanosheets. The morphology and microstructure of the heterojunction photocatalysts were identified by XRD, SEM, TEM, XPS, and BET. The g-C3N4 nanosheets have huge surface area over 200 m2/g and abundant mesoporous ranging from 2-20 nm, which provides tremendous contact area for BiVO4 nanoplates. Meanwhile, the introduction of BiVO4 led to red-shift of the absorption spectrum of photocatalyst, which was characterized by UV-vis diffuse reflection spectroscopy (DRS). Compared with pure BiVO4 and g-C3N4, the BiVO4/g-C3N4 heterojunction shows a drastically enhanced photocatalytic activity in degradation of microcystin-LR (MC-LR) in water. The MC-LR could be removed within 15 minutes under the optimal ratio of BiVO4/g-C3N4. The outstanding performance of the photocatalyst is attributed to synergetic effect of interface Z-scheme heterojunction and high active facets {010} of BiVO4 nanoplates, which provides an efficient transfer pathway to separate photoinduced carriers meanwhile endows the photocatalysts with strong redox ability. 相似文献
86.
Lignosulfonate-based polycatecholamine (PCEA-LS) was synthesized by a two-stage approach involving Mannich and catechol–amine reactions, and it was directly used to adsorb Congo red (CR) from the pH-unadjusted aqueous solution. PCEA-LS was characterized using scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FT-IR), thermogravimetric analysis (TGA), and X-ray photoelectron spectroscopy (XPS). Various factors affecting on removal of CR by PCEA-LS were investigated in depth, including contact time, adsorbent dosage, and initial concentration of CR and adsorption temperature. The adsorption kinetics, isotherm, and thermodynamics of PCEA-LS for CR were explored in detail, and then its adsorption mechanism was systematically elucidated. Results indicated that the removal process of CR followed the pseudo-second-order kinetic model, and the isotherm data fitted the Langmuir model well. The maximum adsorption capacity reached 972.6 mg g−1 at 30°C in the pH-unadjusted (pH = 6.25) solution possibly due to the hydrogen bond, π–π stacking, and electrostatic interaction between PCEA-LS and CR. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020 , 137, 48640. 相似文献
87.
AbstractThe reabsorption characteristics of the lignite treated by low and high temperature drying process were addressed in the paper. The information about the moisture form, functional groups, effective water-filled porosities and equilibrium moisture content of the lignite before and after the drying process was investigated using Differential scanning calorimetry (DSC), Fourier transform infrared (FTIR) spectroscopy, nuclear magnetic resonance (NMR) spectroscopy and a self-made reabsorption device, respectively. The results show that the low drying temperature (140, 190, 230?°C, 10?min, N2) has little impact on the effective water-filled porosities of the resulted samples, whereas it has a great influence on the main oxygen-containing functional groups, which amount firstly decreases and then increases with the drying temperature increasing. In the case of the lignite samples dried under high-temperature (600, 700, 800?°C, 30?s, N2), the amount of the effective water-filled porosity of the sample decreases and the amount of oxygen-containing functional groups increases as the temperature increasing. The reabsorption capability of the high temperature dried sample is much lower than that of the sample treated under low drying temperature. The reabsorption characteristics of the low-temperature dried samples are affected by the amount of the oxygen-containing functional groups, while the effective water-filled porosity is main factor for the lignite samples derived from high temperature drying process. Moreover, the work gives a good evidence that the high-temperature drying process is an effective choose for lignite upgrading. 相似文献
88.
89.
Science China Technological Sciences - Neural network based deep learning methods aim to learn representations of data and have produced state-of-the-art results in many natural language processing... 相似文献
90.
Sowoon Seo Yunjeong Song Sun Mi Gu Hyun Kyu Min Jin Tae Hong Hye Jin Cha Jaesuk Yun 《International journal of molecular sciences》2020,21(23)
Background: Epilepsy is a chronic neurological disorder characterized by the recurrence of seizures. One-third of patients with epilepsy may not respond to antiseizure drugs. Purpose: We aimed to examine whether D-limonene, a cyclic monoterpene, exhibited any antiseizure activity in the pentylenetetrazole (PTZ)-induced kindling mouse model and in vitro. Methods: PTZ kindling mouse model was established by administering PTZ (30 mg/kg) intraperitoneally to mice once every 48 h. We performed immunoblot blots, immunohistochemistry (IHC), and high-performance liquid chromatography (HPLC) analysis after the behavioral study. Results: An acute injection of PTZ (60 mg/kg) induced seizure in mice, while pretreatment with D-limonene inhibited PTZ-induced seizure. Repeated administration of PTZ (30 mg/kg) increased the seizure score gradually in mice, which was reduced in D-limonene (10 mg/kg)-pretreated group. In addition, D-limonene treatment increased glutamate decarboxylase-67 (GAD-67) expression in the hippocampus. Axonal sprouting of hippocampal neurons after kindling was inhibited by D-limonene pretreatment. Moreover, D-limonene reduced the expression levels of Neuronal PAS Domain Protein 4 (Npas4)-induced by PTZ. Furthermore, the adenosine A2A antagonist and ZM241385 inhibited anticonvulsant activity and gamma-aminobutyric acid (GABA)ergic neurotransmission-induced by D-limonene. Conclusion: These results suggest that D-limonene exhibits anticonvulsant activity through modulation of adenosine A2A receptors on GABAergic neuronal function. SCH58261相似文献